Mesoporous ordered titania films: An advanced platform for photocatalysis

光催化 介孔材料 材料科学 纳米技术 异质结 表征(材料科学) 比表面积 多孔性 化学工程 催化作用 化学 复合材料 光电子学 有机化学 工程类
作者
Plinio Innocenzi,Luca Malfatti
出处
期刊:Journal of Photochemistry and Photobiology C-photochemistry Reviews [Elsevier BV]
卷期号:58: 100646-100646 被引量:46
标识
DOI:10.1016/j.jphotochemrev.2023.100646
摘要

Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemical-physical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and self-assembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.
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