Unveiling the Differential Intensity of Fluorous Active Sites Toward Selective Polyfluoroalkyl Substance Removal: Insights into Adsorption and Desorption Trade-Offs

Cl) without structural degradation. Full regeneration (>92% recovery) was achieved with 50% methanol, supporting five reuse cycles with minimal performance decline. In continuous operation, using 1% NaCl achieved a 10-fold PFAS enrichment, while 50% methanol enabled a significantly higher 51-fold enrichment. Both approaches reduced eluent consumption by 20-50% compared to conventional activated carbon and resins. Overall, balancing PFAS adsorption and desorption trade-offs significantly reduces environmental footprint and operational costs, providing a sustainable strategy for PFAS remediation.