Recent Advances in the Design and Application of Asymmetric Carbon‐Based Materials

Abstract Asymmetric carbon‐based materials (ACBMs) have received significant attention in scientific research due to their unique structures and properties. Through the introduction of heterogeneous atoms and the construction of asymmetric ordered/disordered structures, ACBMs are optimized in terms of electrical conductivity, pore structure, and chemical composition and exhibit multiple properties such as hydrophilicity, hydrophobicity, optical characteristics, and magnetic behavior. Here, the recent research progress of ACBMs is reviewed, focusing on the potential of these materials for electrochemical, catalysis, and biomedical applications and their unique advantages over conventional symmetric carbon‐based materials. Meanwhile, a variety of construction strategies of asymmetric structures, including template method, nanoemulsion assembly method, and self‐assembly method, are described in detail. In addition, the contradictions between material synthesis and application are pointed out, such as the limitations of synthesis methods and morphology modulation means, as well as the trade‐off between property improvement and production costs. Finally, the future development path of ACBMs is envisioned, emphasizing the importance of the close integration of theory and practice, and looking forward to promoting the research and development of a new generation of high‐performance materials through the in‐depth understanding of the design principles and action mechanisms of ACBMs.