纳米棒
正交晶系
热液循环
拉曼光谱
单斜晶系
材料科学
纳米颗粒
纳米结构
钨
纳米技术
水热合成
晶体结构
化学工程
透射电子显微镜
形态学(生物学)
结晶学
化学
光学
工程类
物理
生物
冶金
遗传学
出处
期刊:Vietnam Journal of Science and Technology
日期:2018-05-04
卷期号:56 (1A): 127-127
被引量:7
标识
DOI:10.15625/2525-2518/56/1a/12513
摘要
Tungsten oxide nanostructures were synthesized by hydrothermal and acid precipitation (hydrothermal at room temperature) methods without using any supporting agent or structure-directing reactant. The morphology and crystalline structure of nanostructures strongly depended on pH of the precursor solution and synthesis method. With pH = -1.0, using acid precipitation method, orthorhombic nanoplate was observed. Using hydrothermal method, with the pH = - 1.0, we obtained directly stable monoclinic nanoparticle WO3. With pH = 1.1, the mixing of nanoparticle and nanorod with the hexagonal frame was acquired. When pH reaches to 1.7, only bundle of hexagonal nanorods was observed. To characterize the morphology and structure of tungsten nanostructures, we used Field Emission Scanning Electron Microscopy, X-ray diffraction, and micro Raman spectroscopy. The micro Raman spectroscopy was used to support the X-ray diffraction analysis. These results imply that adjusting pH is an efficient and promising method to manipulate both morphology and crystal structure of WO3 nanostructure for selective applications.
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