丙烷
吸附
微型多孔材料
选择性
碳氢化合物
热解
萃取(化学)
化学工程
天然气
碳纤维
化学
材料科学
活性炭
有机化学
催化作用
复合材料
复合数
工程类
作者
Fuqiang Chen,Kaiqing Guo,Xinlei Huang,Zhiguo Zhang,Qiwei Yang,Yiwen Yang,Qilong Ren,Zongbi Bao
标识
DOI:10.1007/s40843-022-2096-8
摘要
The separation of light hydrocarbon mixtures and the extraction of C3H8 and C2H6 from natural gas are of significant importance in natural gas purification and upgrading. Microporous carbon adsorbents are promising in light hydrocarbon separation. However, the fabrication of uniform ultramicropores to boost separation selectivity remains challenging. Herein, we fabricated a series of poly(vinylidene chloride)-resin-derived ultramicroporous carbon adsorbents with a relatively uniform pore size (5.2–5.3 Å) by activator-free pyrolysis. The optimal C-PVDC-800 exhibited record-high ideal adsorption solution theory (IAST) selectivity for C3H8/CH4 (3387) and C2H6/CH4 (75) and Henry’s selectivity for C3H8/CH4 (369) among all reported adsorbents under ambient conditions, combined with ultrahigh uptake of C3H8 (3.9 mmol g−1, 0.05 bar) and C2H6 (2.67 mmol g−1, 0.10 bar) at low partial pressures and 298 K. More importantly, fast gas adsorption kinetics favorable for fixed-bed adsorption applications was realized. Breakthrough experiments and cycling tests further confirm the superb separation performance of the extraction of C3H8 and C2H6 from natural gas.
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