吸附
溴化铵
亚甲蓝
污染物
化学
肺表面活性物质
煅烧
Box-Behnken设计
朗缪尔吸附模型
化学工程
响应面法
核化学
色谱法
有机化学
催化作用
光催化
工程类
生物化学
作者
Chaoli Chen,Jinyuan Ma,Yong Wang,Zao Yi,Shifa Wang,Huajing Gao,Xianwen Wu,Guorong Liu,Hua Yang
标识
DOI:10.1016/j.colsurfa.2022.130441
摘要
Herein we have synthesized Bi2MoO6 (BMO) hierarchical microspheres via a solvothermal method using hexadecyl trimethyl ammonium bromide (CTAB) as surfactant, and demonstrated that the synthesized BMO can be used as an efficient and recyclable adsorbent for removing organic pollutants. By using methylene blue (MB) as the target pollutant, the adsorption kinetics, adsorption isotherms and adsorption thermodynamics of MB onto the BMO adsorbent were systematically investigated. The effects of pH, temperature and adsorbent dosage on the MB adsorption by BMO were predicted by response surface methodology (RSM) with Box-Behnken design (BBD). It is interestingly demonstrated that the BMO adsorbent can be easily regenerated via a simple calcination process in air and exhibits excellent reusability. To promote the practical application of the BMO adsorbent in water purification, we have further compared its adsorption capability in removing 18 kinds of organic pollutants (including various organic dyes, antibiotics and other serious organic pollutants) at different acidic-alkaline environments. In the normal and alkaline (pH 12) environments, the highest adsorption is observed for Congo red (CR) with qe = 216.331 and 232.723 mg g−1, respectively; whereas in the acidic environment (pH 2), the highest adsorption is observed for eriochrome black T (EBT) with qe = 64.362 mg g−1. Based on the experimental results, the involved adsorption mechanism was analyzed.
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