阳极
锂(药物)
电极
四氰基对醌二甲烷
材料科学
离子
氧化还原
无机化学
纳米技术
化学工程
化学
分子
物理化学
有机化学
冶金
内分泌学
工程类
医学
作者
Chao Meng,Tianhui Chen,Chun Fang,Yunhui Huang,Pinfei Hu,Yongli Tong,Ting Bian,Jiaojiao Zhang,Zhaoxuan Wang,Aihua Yuan
标识
DOI:10.1002/asia.201901190
摘要
Recently, carboxylate metal-organic framework (MOF) materials were reported to perform well as anode materials for lithium-ion batteries (LIBs); however, the presumed lithium storage mechanism of MOFs is controversial. To gain insight into the mechanism of MOFs as anode materials for LIBs, a self-supported Cu-TCNQ (TCNQ: 7,7,8,8-tetracyanoquinodimethane) film was fabricated via an in situ redox routine, and directly used as electrode for LIBs. The first discharge and charge specific capacities of the self-supported Cu-TCNQ electrode are 373.4 and 219.4 mAh g-1 , respectively. After 500 cycles, the reversible specific capacity of Cu-TCNQ reaches 280.9 mAh g-1 at a current density of 100 mA g-1 . Mutually validated data reveal that the high capacity is ascribed to the multiple-electron redox conversion of both metal ions and ligands, as well as the reversible insertion and desertion of Li+ ions into the benzene rings of ligands. This work raises the expectation for MOFs as electrode materials of LIBs by utilizing multiple active sites and provides new clues for designing improved electrode materials for LIBs.
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