离子液体
化学
C4毫米
低临界溶液温度
拉曼光谱
金属
分析化学(期刊)
相(物质)
无机化学
催化作用
色谱法
有机化学
共聚物
光学
物理
聚合物
作者
Zailai Xie,Andreas Taubert
出处
期刊:ChemPhysChem
[Wiley]
日期:2010-12-29
卷期号:12 (2): 364-368
被引量:56
标识
DOI:10.1002/cphc.201000808
摘要
The iron-containing ionic liquids 1-butyl-3-methylimidazolium tetrachloroferrate(III) [C(4)mim][FeCl(4)] and 1-dodecyl-3-methylimidazolium tetrachloroferrate(III) [C(12)mim][FeCl(4)] exhibit a thermally induced demixing with water (thermomorphism). The phase separation temperature varies with IL weight fraction in water and can be tuned between 100 °C and room temperature. The reversible lower critical solution temperature (LCST) is only observed at IL weight fractions below ca. 35 % in water. UV/Vis, IR, and Raman spectroscopy along with elemental analysis prove that the yellow-brown liquid phase recovered after phase separation is the starting IL [C(4)mim][FeCl(4)] and [C(12)mim][FeCl(4)], respectively. Photometry and ICP-OES show that about 40 % of iron remains in the water phase upon phase separation. Although the process is thus not very efficient at the moment, the current approach is the first example of an LCST behavior of a metal-containing IL and therefore, although still inefficient, a prototype for catalyst removal or metal extraction.
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