镍
过电位
析氧
X射线光电子能谱
电化学
金属
电解质
化学工程
分解水
材料科学
过渡金属
无机化学
化学
冶金
光催化
电极
有机化学
催化作用
物理化学
工程类
作者
Bi‐Liu Lan,Lei Lei,Fujie Yang,Wei Pang,Zeping Guo,Ting Meng,Zhong Zhang,Jin Huang
标识
DOI:10.1002/sstr.202200085
摘要
Accurate introduction of catalytic active sites to precise locations on the catalyst surface is a challenge in designing and synthesizing high‐efficiency catalysts. Herein, the α phase nickel–iron oxyhydroxide ( α ‐NiFeO x H y ) rich of nickel active edge sites is electrochemically in situ generated from Fe‐square acid metal–organic framework precursor deposited on nickel‐containing electrode matrixes, which revealed superior oxygen evolution reaction performance signified by an overpotential of 167 mV to achieve a current density of 10 mA cm −2 in alkaline electrolytes. Notably, the as‐prepared metal oxyhydroxide exhibits long‐term electrochemical durability in 10 mA cm −2 for over 1080 h. By integrating the electrochemical evidence, Mössbauer spectroscopy, X‐Ray photoelectron spectroscopy, and density functional theory calculations, the nickel species enriched on the exposed edge facet of the as‐synthesized α ‐NiFeO x H y are proposed to be the highly catalytic active site. This study provides an expedient and energy‐efficient approach to in situ electrochemical fabrication of high‐performance NiFeO x H y oxygen evolution reaction catalysts from metal‐organic frameworks.
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