材料科学
光催化
催化作用
选择性
卟啉
氮化碳
光化学
量子点
纳米技术
化学工程
化学
有机化学
工程类
作者
Cheng Zheng,Xueying Qiu,Jianyu Han,Yafeng Wu,Songqin Liu
标识
DOI:10.1021/acsami.9b15306
摘要
It is urgent yet challenging to develop photocatalysts for visible-light-driven CO2 reduction with high efficiency and selectivity. Here, we report a novel hybrid catalyst by coordinating zero-dimensional (0D) carbon nitride quantum dots (g-CNQDs) with two-dimensional (2D) ultrathin porphyrin MOF (PMOF). Different from previously reported hybrid catalysts combined through physical or electrostatic interactions, in our prepared g-CNQDs/PMOF hybrids, g-CNQDs are coordinated with Co active sites in PMOF, which significantly shortens the migrating pathway of both photogenerated charge carriers and gaseous substrates from g-CNQDs to Co active centers. The resulting efficient electron-hole pair separation and long-lived trapped electrons at Co centers not only boost the photocatalytic CO2 reduction activity but also improve its selectivity for the eight-electron reduced product CH4. To our knowledge, this is the first example of a hybrid catalyst combined through coordination interaction. Remarkably, the prepared hybrid catalyst exhibits a 2.34-fold enhancement in the CO generation rate (16.10 μmol g-1 h-1) and a 6.02-fold enhancement in the CH4 evolution rate (6.86 μmol g-1 h-1) compared to the bare PMOF.
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