材料科学
双环戊二烯
气凝胶
碳纳米管
复合材料
电磁干扰
纳米片
石墨烯
电磁屏蔽
电磁干扰
聚合
纳米复合材料
聚合物
纳米技术
电子工程
工程类
作者
Ping Wang,Yang Li,Jiacheng Ling,Jie Song,Tao Song,Xinliang Chen,Shang Gao,Shaojie Feng,Yi Ding,Vignesh Murugadoss,Mina Huang,Zhanhu Guo
标识
DOI:10.1007/s42114-022-00543-x
摘要
In order to solve the problem of electromagnetic radiation and interference, improving the electromagnetic interference shielding effectiveness (EMI SE) of polymer nanocomposites is still an arduous challenge. Three-dimensional (3D) lightweight porous carbon nanotube/graphene nanosheet aerogels (CNT/GN) were prepared by freeze-drying method. The CNT/GN conductive framework template was filled with dicyclopentadiene (DCPD), and the polydicyclopentadiene (PDCPD)-CNT/GN composites were prepared by frontal ring-opening metathesis polymerization (FROMP). Compared with PDCPD-CNT/GN-1 (the GN-1 diameter of 0.5 ~ 1 µm), the PDCPD-CNT/GN-2 (the GN-2 diameter of 1 ~ 2 µm) can form a more regular and compact conductive network structure, thereby achieving higher EMI shielding effectiveness (SE). The 3D framework not only solves the aggregation of CNT and GN, but also serves as a fast channel for electronic transmission, attenuating the incoming electromagnetic waves. Due to the existence of this 3D nano-hybrid framework, the PDCPD-3CNT/2GN-2 composites containing 3.5 wt% of 3CNT/2GN-2 aerogel exhibit the conductivity of 61 S/m and EMI SE of 43 dB. All PDCPD-CNT/GN composites possess a high glass transition temperature (Tg) above 150 ℃ and maintain excellent thermal stability.Graphical abstract
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