硒化物
卤化物
化学
烷基
溶剂
钠
反应条件
组合化学
硒化铅
硒
有机化学
纳米技术
材料科学
催化作用
作者
Na Hye Shin,Yoo Jin Lim,Chorong Kim,Ye Eun Kim,Yu Ra Jeong,Hyunsung Cho,Myung-Sook Park,Sang Hyup Lee
出处
期刊:Molecules
[MDPI AG]
日期:2022-08-16
卷期号:27 (16): 5224-5224
被引量:2
标识
DOI:10.3390/molecules27165224
摘要
The studies on the selective synthesis of dialkyl selenide compounds 1 were presented. Overcoming the complexity and difficulty of selenides (R-Se-R) and/or multiselenides (R-Sen-R; n ≥ 2), we aimed to optimize the reaction condition for the tolerable preparation of sodium selenide (Na2Se) by reducing Se with NaBH4, and then to achieve selective syntheses of dialkyl selenides 1 by subsequently treating the obtained sodium selenide with alkyl halides (RX). Consequently, various dialkyl selenides 1 were efficiently synthesized in good-to-moderate yields. The investigations on reaction pathways and solvent studies were also described.
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