Hydrothermally synthesized TiO2 doped MnO2 nanocomposites for Electrochemical and photocatalytic activity

材料科学 光催化 纳米复合材料 兴奋剂 电化学 化学工程 热液循环 纳米技术 电极 光电子学 催化作用 有机化学 物理化学 化学 工程类
作者
N. Vidhya N. Vidhya,S. Pari,R. Uthrakumar,C. Inmozhi,K. Kaviyarasu,Tanveer Ahmad Mir,Sajid Ali Ansari,Mir Waqas Alam
出处
期刊:NANO [World Scientific]
被引量:5
标识
DOI:10.1142/s1793292024501431
摘要

In our study, we synthesize titanium oxide (TiO[Formula: see text] and manganese dioxide (MnO[Formula: see text] using hydrothermal methods, which are TiO 2 -doped MnO 2 nanoparticles. In order to evaluate the essential optical and electronic properties of the proposed nanostructures, X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transformation infrared analysis (FTIR), Ultra–Visible infrared spectroscopy (UV–Vis), and Photoluminescence (PL) were applied. Based on the results of the SEM investigation, nanostructures form crystal structures when different compositions are used. It was also confirmed that TiO 2 derivatives were produced from the fabricated nanoparticles by their spectral and optical absorption characteristics. During electrochemical measurements, it was found that MnO 2 nanocomposite samples doped with TiO 2 had a markedly reduced charge transfer resistance, suggesting that electrons and holes were effectively separated by photo-stimulation. Aqueous solutions based on wastewater were shown to be degraded by TiO 2 -doped MnO 2 nanoparticles when irradiated with visible light. It was demonstrated that nanocomposites composed of TiO 2 -doped with MnO 2 and having reduced bandgap could be used for the removal of organic dyes from aqueous solutions as well as wastewater treatment were reported in detail.
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