化学
镍
反应性(心理学)
配体(生物化学)
氮原子
钳形配体
氮气
Atom(片上系统)
钳子运动
立体化学
结晶学
光化学
催化作用
有机化学
群(周期表)
受体
生物化学
医学
替代医学
病理
计算机科学
嵌入式系统
作者
Changguang Yao,Théo P. Gonçalves,Xiufang Wang,Lun Luo,Kuo‐Wei Huang
标识
DOI:10.1021/acs.inorgchem.4c00429
摘要
Room-temperature photoactivation of the first- and second-generation PN3P-pincer nickel azido complexes 1a and 1b in the presence of CO2 or CS2 afforded N-bound carbamates, dithiocarbamates, and isothiocyanates, providing insights into CO2 and CS2 activation and demonstrating how a seemingly small difference in the ligand structure significantly influences the reactivity. Theoretical calculations disclosed that the charge of the phosphorus atom plays a critical role in determining the nitrogen atom transfer to form a plausible nickel phosphiniminato intermediate.
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