环戊二烯基络合物
镧系元素
化学
阳离子聚合
金属有机化学
铈
反应性(心理学)
卡宾
位阻效应
茂金属
二价
环戊二烯
主组元素
高分子化学
聚合
有机化学
无机化学
催化作用
过渡金属
聚合物
离子
病理
替代医学
医学
标识
DOI:10.1002/9780470824870.ch8
摘要
This charpter summerized the main progress in organolanthanide chemistry in recent years, including the synthesis and reactivity of organolanthanide π-complexes stablized by cyclopentadienyl and substituted cyclopentadienyl as well as allyl groups, lanthanide alkyls, hydrides, cationic alkyl complexes, N-heterocyclic carbene complexes supported by cyclopentadienyl and non-cyclopentadienyl groups, non-class divalent lanthanide metals complexes and sterically induced reduction chemistry, and tetravalent cerium complexes, as well as their applications as homogenous catalysts in organic transformation and polymerization.
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