硫代氨基甲酸酯类
硫代氨基甲酸酯
化学
电化学
惰性气体
组合化学
惰性
金属
连续流动
纳米技术
有机化学
电极
生化工程
工程类
物理化学
材料科学
作者
Bhanwar Kumar Malviya,Ved Prakash Verma,Siddharth Sharma
摘要
An expeditious synthetic strategy to access functionalized S-thiocarbamates was developed in good to excellent yields and with high current efficiencies. Readily available isocyanides and thiols were used as the starting materials under simple metal- and oxidant-free reaction conditions avoiding an inert atmosphere. The practical application of the present methodology was achieved by electrochemical synthesis of the herbicides prosulfocarb and pebulate. Furthermore, continuous electrochemical flow conditions using a graphite/Pt flow cell were used to obtain S-thiocarbamate compounds on a gram scale within a residence time of 35 min.
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