Boosting Selective Oxidation of Ethylene to Ethylene Glycol Assisted by In situ Generated H2O2 from O2 Electroreduction

Abstract Ethylene glycol is a useful organic compound and chemical intermediate for manufacturing various commodity chemicals of industrial importance. Nevertheless, the production of ethylene glycol in a green and safe manner is still a long‐standing challenge. Here, we established an integrated, efficient pathway for oxidizing ethylene into ethylene glycol. Mesoporous carbon catalyst produces H 2 O 2 , and titanium silicalite‐1 catalyst would subsequently oxidize ethylene into ethylene glycol with the in situ generated H 2 O 2 . This tandem route presents a remarkable activity, i.e., 86 % H 2 O 2 conversion with 99 % ethylene glycol selectivity and 51.48 mmol g ecat −1 h −1 production rate at 0.4 V vs. reversible hydrogen electrode. Apart from generated H 2 O 2 as an oxidant, there exists ⋅OOH intermediate which could omit the step of absorbing and dissociating H 2 O 2 over titanium silicalite‐1, showing faster reaction kinetics compared to the ex situ one. This work not only provides a new idea for yielding ethylene glycol but also demonstrates the superior of in situ generated H 2 O 2 in tandem route.