热重分析
催化作用
材料科学
X射线光电子能谱
傅里叶变换红外光谱
环辛烯
薄膜
金属有机骨架
扫描电子显微镜
化学工程
核化学
无机化学
纳米技术
物理化学
有机化学
化学
复合材料
吸附
工程类
作者
Fatemeh Moghadaskhou,Azadeh Tadjarodi,Afsaneh Mollahosseini,Ali Maleki
标识
DOI:10.1021/acsami.2c18907
摘要
Metal-organic frameworks (MOFs), particularly UiO-66-NH2, are employed as a catalyst in many industrial catalyst applications. As converting catalysts into thin film significantly increases their catalytic properties for the epoxidation of olefins, we report a general approach to synthesizing MOF thin films (UiO-66-Sal-Cu(OH)2). Using the postsynthesis method (PSM), UiO-66-NH2 was functionalized with salicylaldehyde and entrapped on copper hydroxide nanoparticle surfaces using a modern strategy (MOF thin film). We used field-emission scanning electron microscopy (FE-SEM), EDX (energy-dispersive X-ray analysis), XRD (X-ray diffraction), FT-IR (Fourier transform infrared), BET (Brunauer-Emmett-Teller), TGA (thermogravimetric analysis), XPS (X-ray photoelectron spectroscopy), and ICP-MS (inductively coupled plasma mass spectrometry) to determine the structure and morphology of the synthesized UiO-66-Sal-Cu(OH)2. The oxidation of cyclooctene by the UiO-66-Sal-Cu(OH)2 thin film was studied. Due to its advantages, such as being environmentally friendly (base metal-loaded catalyst, room temperature, solvent-free reaction), reusability, and high yield, this compound can be an appropriate catalyst for the oxidation of olefins.
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