AlN Thin-Film Vacuum Ultraviolet Photodetector With High Operating Temperature and High Rejection Ratio

AlN thin-film vacuum ultraviolet (VUV) photodetector was prepared by molecular beam epitaxy (MBE) device on ${c}$ -Al2O3 substrate. By a complete surface nitridation of sapphire substrate in nitrogen plasma, the epitaxial preparation of high-quality thin AlN film was realized without any buffer layer. The AlN photodetector has an ultralow dark current (~40 fA at 20 V), a high VUV/ultraviolet-c (UVC) ( ${R}_{{185}}/{R}_{{222}}$ ) rejection ratio ( $10^{{3}}$ ), a high responsivity (30 mA/W), and an ultrafast response (90%–10% decay time ~900 ns) at room temperature. More interestingly, an excellent temperature tolerance of the device can be observed, and there is no obvious degradation in the VUV/UVC rejection ratio and response speed with increasing the temperature from 25 °C to 500 °C. Even at 500 °C, the dark current of the device is only 218 pA at 20 V, and the responsivity can reach to 67.3 mA/W. These results indicate that the device has excellent wavelength selective detection ability and high-temperature detection ability in the VUV band, which can be attributed to the relatively high-quality AlN thin film and the avoidance of the impact of buffer layer. Our findings provide an effective way to realize high-performance AlN VUV photodetector, which can be operated in high-temperature environment.