卤化物
发光二极管
纳米晶
材料科学
钙钛矿(结构)
光电子学
二极管
带隙
量子效率
纳米技术
化学
无机化学
结晶学
作者
Ah‐Young Lee,Jong Hyun Park,Hongju Kim,Hu Young Jeong,Jun Hee Lee,Myoung Hoon Song
出处
期刊:Small
[Wiley]
日期:2022-11-10
卷期号:18 (52)
被引量:2
标识
DOI:10.1002/smll.202205011
摘要
Abstract Metal halide perovskites (MHPs) have gained traction as emitters owing to their excellent optical properties, such as facile bandgap tuning, defect tolerance, and high color purity. Nevertheless, blue‐emitting MHP light‐emitting diodes (LEDs) show only marginal progress in device efficiency compared with green and red LEDs. Herein, the origin of the drop in efficiency of blue‐emitting perovskite nanocrystals (PNCs) by mixing halides and the genesis of Ruddlesden–Popper faults (RPFs) in CsPbBr X Cl 3‐X nanocrystals is investigated. Using scanning transmission electron microscopy and density functional theory calculations, the authors have found that RPFs induce possible nonradiative recombination pathways owing to the high chloride vacancy concentration nearby. The authors further confirm that the blue‐emitting PNCs do not show RPFs post‐halide exchange in the CsPbBr 3 nanocrystals. By introducing the post‐halide exchange treatment, high‐efficiency pure blue‐emitting (464 nm) PNC‐based LEDs with an external quantum efficiency of 2.1% and excellent spectral stability with a full‐width at half‐maximum of 14 nm are obtained.
科研通智能强力驱动
Strongly Powered by AbleSci AI