臭氧
环境科学
氮氧化物
中国
化学输运模型
空气质量指数
大气科学
气候学
空气污染
平流
污染
气象学
地理
化学
生物
生态学
物理
有机化学
考古
地质学
热力学
燃烧
作者
Ya Ni,Yang Yang,Hailong Wang,Huimin Li,Mengyun Li,Pinya Wang,Ké Li,Hong Liao
标识
DOI:10.1016/j.scitotenv.2023.168272
摘要
Ozone pollution is one of the most severe air quality issues in China that poses a serious threat to human health and ecosystems. During 2019-2021, the maximum daily 8-h average ozone concentrations in eastern China (110-122.5°E, 26-42°N) and the rest of China (ROC) show different decreasing patterns, with ozone concentrations in eastern China decreasing by 14.9 μg/m3, which is much larger than 4.8 μg/m3 in ROC. Here, based on two independent methods, the atmospheric chemical transport model (GEOS-Chem) simulations and the machine learning (ML) model (LightGBM) predictions, the reasons for the differences in ozone changes between eastern China and ROC during the warm season (April to September) are investigated. According to the GEOS-Chem (LightGBM) results, changes in the meteorological conditions contributed to an ozone decrease by 7.3 (6.8) μg/m3 in eastern China due to decreased chemical production and an ozone decrease by 6.8 (7.0) μg/m3 in ROC attributed to the weakened horizontal and vertical advection. With the influence of meteorological factors excluded, the observations show that changes in anthropogenic emissions resulted in an ozone decrease by 7.6 (8.1) μg/m3 in eastern China and an ozone increase by 2.0 (2.2) μg/m3 in ROC, which is primarily induced by the changes in NOx emissions. The surface measurements and satellite retrievals also indicate that the reduction in NOx emissions in ROC is less efficient than that in the more developed eastern China, leading to contrasting changes in ozone concentrations between eastern China and ROC during 2019-2021. Our results highlight the critical need to reduce ozone precursor emissions in the rest regions of China apart from eastern China.
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