兴奋剂
钙钛矿(结构)
材料科学
光致发光
量子产额
锡
发光二极管
SN2反应
二极管
光电子学
光化学
化学工程
结晶学
化学
荧光
立体化学
光学
冶金
工程类
物理
作者
Yongqi Zhang,Haiying Cheng,Xin Chen,Yuanhui Zheng
标识
DOI:10.1021/acs.jpcc.3c05145
摘要
Two-dimensional (2D) Sn-based perovskites have emerged as a promising alternative to Pb-based perovskites due to their nontoxic nature. However, Sn2+ ions tend to get oxidized to Sn4+ during the synthesis process, leading to crystalline defects and rapid nonradiative transitions, which limits their applications. In this study, we present a facile molecular doping strategy for (C18H35NH3)2SnBr4 perovskite by introducing o-phenylenediamine (oPD) in the precursor solution. The oPD serves a dual role: it not only acts as an electron donor, creating a reducing environment to suppress the oxidation of Sn2+, but also functions as a chelating agent, forming stable compounds with Sn2+. This approach results in 20% oPD doped (C18H35NH3)2SnBr4 perovskite, which exhibits a high photoluminescence quantum yield (PLQY) of 95.3% and excellent stability against oxygen. Furthermore, UV-pumped orange and white light-emitting diodes (LEDs) with a CIE coordinate (0.562, 0.431, 0.327, and 0.346) were produced using oPD-doped 2D tin-based perovskite powders, respectively. These findings suggest that the doping strategy has great potential to enhance the stability of 2D Sn-based perovskites and facilitate their application in the field of lighting devices.
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