化学
胺化
反应性(心理学)
可见光谱
表面改性
光化学
组合化学
有机化学
催化作用
物理化学
光电子学
医学
物理
病理
替代医学
作者
Igor Jurberg,RENE NOME,Stefano Crespi,Teresa Atvars,Burkhard Koenig
标识
DOI:10.1002/adsc.202201095
摘要
A two-step protocol allowing the C-H amination of cyclic ethers with iminoiodinanes, followed by the reduction of the resulting intermediate has been developed for the preparation of amino alcohols. The initial C-H functionalization is accelerated by visible light, improving the reactivity compared to the thermal process performed in the dark. The effect of different substituents on the photochemical reactivity of iminoiodinanes has been studied both experimentally and computationally. Photophysical measurements and DFT calculations were performed to better understand the observed reactivities and corroborate the proposed mechanistic proposal.
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