纳米复合材料
材料科学
聚吡咯
碳纳米管
傅里叶变换红外光谱
聚合
结晶度
聚合物
化学工程
扫描电子显微镜
复合材料
导电聚合物
聚合物纳米复合材料
高分子化学
工程类
作者
P. Saheeda,S. Jayaleksmi
标识
DOI:10.1016/j.optmat.2020.109940
摘要
Nanocomposite of polypyyrole (PPy) and multi walled carbon nanotubes (MWCNTs) is synthesized via liquid/liquid interfacial polymerization, where polymerization takes place at the interface of aqueous and organic phases. Scanning electron microscopy (SEM) images of the composite show that functionalized carbon nanotubes (CNTs) are wrapped by the polymer and the former are homogeneously dispersed in the polymer matrix. The high degree of crystallinity observed in the XRD plot of the nanocomposite indicates good extent of structural ordering during the formation of the nanocomposite. Fourier transform infrared (FTIR) spectroscopy and UV–visible absorption spectroscopy studies reveal the strong inter facial interaction between the polymer and the CNTs. The electrical conductivity of the nanocomposite is found to be enhanced to 8.05 S cm-1 from the value of 2.03 × 10−2 S cm-1 for polypyrrole. The nonlinear optical properties associated with the nanocomposite are studied using single beam Z-scan set up and the results confirm appreciable nonlinear optical response of the composite compared to pure polypyrrole. The studies also establish the potential applications of this nanocomposite as efficient optical limiters.
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