纳滤
溶剂
离子液体
界面聚合
膜
渗透
聚合
高分子化学
聚丙烯腈
单体
薄膜复合膜
相位反转
化学
化学工程
耐化学性
溶解度参数
材料科学
有机化学
反渗透
聚合物
催化作用
渗透
工程类
生物化学
作者
Kunkai Ma,Xiaoshuang Li,Xianger Xia,Yezhen Chen,Zhenchao Luan,Hongyue Chu,Bo Geng,Mei Yan
标识
DOI:10.1016/j.memsci.2023.121486
摘要
The preparation of solvent resistant nanofiltration (SRNF) membranes with high permeance and retention is required for accurate chemical separation, yet the solvent resistance of the membranes still needs to be improved. Fluoropolymers with strong weather resistance and chemical stability are expected to improve the solvent resistance of solvent resistant nanofiltration membranes. However, the application of fluorinated monomers in interfacial polymerization has been limited because they are water-insoluble. In this paper, ionic liquids were added to the aqueous phase to improve the solubility of hexafluorobisphenol A (BPAF). Trimesoyl chloride (TMC) was used as organic phase monomer. Fluorinated polyarylester thin film composite (TFC) membranes were synthesized on polyacrylonitrile (PAN) base membranes utilizing interfacial polymerization. The results confirmed that the surface morphology and roughness of TFC membranes could be regulated by adding fluorinated monomer. The membrane sample PAN-F-0.5 exhibits a high permeance for methanol up to 124.05 L m−2 h−1 bar−1. The resulting membrane possesses a molecular weight cut off (MWCO) of∼450 g mol−1. PAN-F-0.5 still showed excellent performance after continuous immersion in DMF for 90 days (room temperature) and 7 days (80 °C), respectively. The results show that the TFC membrane has excellent filtration performance and solvent resistance.
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