对偶(语法数字)
催化作用
机制(生物学)
Boosting(机器学习)
双重角色
化学
纳米技术
材料科学
化学工程
组合化学
计算机科学
生物化学
物理
艺术
文学类
量子力学
机器学习
工程类
作者
Siran Xu,Sihua Feng,Yue Yu,Dongping Xue,Mengli Liu,Chao Wang,Kaiyue Zhao,Bingjun Xu,Jianan Zhang
标识
DOI:10.1038/s41467-024-45700-6
摘要
Abstract Efficient oxygen evolution reaction electrocatalysts are essential for sustainable clean energy conversion. However, catalytic materials followed the conventional adsorbate evolution mechanism (AEM) with the inherent scaling relationship between key oxygen intermediates *OOH and *OH, or the lattice-oxygen-mediated mechanism (LOM) with the possible lattice oxygen migration and structural reconstruction, which are not favorable to the balance between high activity and stability. Herein, we propose an unconventional Co-Fe dual-site segmentally synergistic mechanism (DSSM) for single-domain ferromagnetic catalyst CoFeS x nanoclusters on carbon nanotubes (CNT) (CFS-ACs/CNT), which can effectively break the scaling relationship without sacrificing stability. Co 3+ (L.S, t 2g 6 e g 0 ) supplies the strongest OH* adsorption energy, while Fe 3+ (M.S, t 2g 4 e g 1 ) exposes strong O* adsorption. These dual-sites synergistically produce of Co-O-O-Fe intermediates, thereby accelerating the release of triplet-state oxygen ( ↑ O = O ↑ ). As predicted, the prepared CFS-ACs/CNT catalyst exhibits less overpotential than that of commercial IrO 2 , as well as approximately 633 h of stability without significant potential loss.
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