Electrochemical determination of ascorbic acid using palladium supported on N-doped graphene quantum dot modified electrode

Abstract To precise screening concentration of ascorbic acid (AA), a novel electrochemical sensor was prepared using palladium nanoparticles decorated on nitrogen-doped graphene quantum dot modified glassy carbon electrode (PdNPs@N-GQD/GCE). For this purpose, nitrogen doped GQD nanoparticles (N-GQD) were synthesized from a citric acid condensation reaction in the presence of ethylenediamine and subsequently modified by palladium nanoparticles (PdNPs). The electrochemical behavior of AA was investigated, in which the oxidation peak appeared at 0 V related to the AA oxidation. Considering the synergistic effect of Pd nanoparticles as an active electrocatalyst, and N-GQD as an electron transfer accelerator and electrocatalytic activity improving agent, PdNPs@N-GQD hybrid materials showed excellent activity in the direct oxidation of AA. In the optimal conditions, the voltammetric response was linear in the range from 30 to 700 nM and the detection limit was calculated to be 23 nM. The validity and the efficiency of the proposed sensor were successfully tested and confirmed by measuring AA in real samples of chewing tablets, and fruit juice.