激发态
简并能级
有机发光二极管
量子效率
树枝状大分子
兴奋剂
化学
荧光
光电子学
热平衡
光化学
热的
材料科学
原子物理学
纳米技术
物理
光学
高分子化学
量子力学
热力学
图层(电子)
作者
Martin R. Bryce,Chensen Li,Alastair K. Harrison,Yuchao Liu,Zhennan Zhao,Cheng Zeng,Fernando Braga Stehling Dias,Zhongjie Ren,Shouke Yan
标识
DOI:10.1002/anie.202115140
摘要
The mechanism of thermally activated delayed fluorescence (TADF) in dendrimers is not clear. We report that fully-conjugated or fully-nonconjugated structures cause unwanted degenerate excited states due to multiple identical dendrons, which limit their TADF efficiency. We have synthesized asymmetrical "half-dendronized" and "half-dendronized-half-encapsulated" emitters. By eliminating degenerate excited states, the triplet locally excited state is ≥0.3 eV above the lowest triplet charge-transfer state, assuring a solely thermal equilibrium route for an effective spin-flip process. The isolated encapsulating tricarbazole unit can protect the TADF unit, reducing nonradiative decay and enhancing TADF performance. Non-doped solution-processed devices reach a high external quantum efficiency (EQEmax ) of 24.0 % (65.9 cd A-1 , 59.2 lm W-1 ) with CIE coordinates of (0.24, 0.45) with a low efficiency roll-off and EQEs of 23.6 % and 21.3 % at 100 and 500 cd m-2 .
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