超级电容器
杂原子
碳化
硫黄
比表面积
氮气
碳纤维
材料科学
润湿
多孔性
化学工程
储能
功率密度
纳米技术
化学
电容
有机化学
复合材料
复合数
电极
工程类
催化作用
扫描电子显微镜
冶金
物理化学
戒指(化学)
功率(物理)
物理
量子力学
作者
Ghazanfar Nazir,Adeela Rehman,Sajjad Hussain,Muhammad Ikram,Soo‐Jin Park
摘要
Herein, the banana-peel waste was carbonized followed by KOH activation to design novel N, S-co-doped hierarchically porous carbonaceous materials (NS-AC). The synthesized sample (NS-AC) exhibited an interconnected porosity and endowed with a high specific surface area (SSA ~ 2452 m2 g−1), total pore volume (Vtotal ~ 1.82 cm3 g−1), and moderate nitrogen (3.2 at%) and sulfur (0.6 at%) contents. Moreover, these carbons, when scrutinized as electrode materials, demonstrated a specific capacitance (220 F g−1 at 0.5 A g−1), which persists at 145 F g−1 even at a large current density of 6 A g−1, thereby demonstrating an efficient rate capability. Furthermore, a capacitance retention of ~78.2% over 15 000 cycles was also observed. All these characteristics reveal NS-AC carbons a promising contender for energy storage. Finally, as-prepared symmetric supercapacitor (NS-AC/NS-AC) exhibited remarkable energy density ~5.3 Wh kg−1 at a power density of 2690 W kg−1 with capacitance retention of 88% over 4000 charge/discharge cycles, which surpasses the working performance of the many reported carbon materials obtained from biomass sources. In conclusion, outstanding textural features and enhanced conductivity by KOH activation, in addition to the improved surface wettability posed by N- and S-enriched surfaces, resulted in considerable supercapacitor performance. Highlights Banana peels-derived biochar-based porous carbons Porous carbons exhibit large specific surface area (>2452 m2 g−1). Binary heteroatom-doped carbons possess at% of N (3.2) and S (0.6). Synergetic effect of N and S doping and high porosity leads to high supercapacitance.
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