材料科学
普鲁士蓝
超级电容器
碳化
化学工程
蚀刻(微加工)
磷化物
电化学
过渡金属
氧化物
功率密度
电阻率和电导率
纳米技术
电极
金属
复合材料
冶金
化学
催化作用
物理化学
有机化学
功率(物理)
扫描电子显微镜
工程类
物理
图层(电子)
电气工程
量子力学
作者
Mengyi Wang,Junhao Zhong,Zhenhua Zhu,Aimei Gao,Fenyun Yi,Jingzhou Ling,Junnan Hao,Dong Shu
标识
DOI:10.1016/j.jallcom.2021.162344
摘要
Transition metal phosphides (TMPs) have attracted great interest owing to the metallic properties and high specific capacities. Here, we designed hollow NiCoP nanocubes with increased specific surface area using a Ni-Co Prussian blue analogue as a self-template and NH3·H2O as an etching agent. During the synthesis, both carbonization and phosphorization are completed in one step. The obtained hollow structure alleviates the volume variation of electrode material during reversible electrochemical reaction. Meanwhile, the residual carbon distributed uniformly in NiCoP at the molecular level, resulting in a high conductivity. DFT calculations further reveal that the electrical conductivity of NiCoP is superior to those of monometallic phosphide and metal oxide. Therefore, the optimized NiCoP-4–500 displays a high specific capacity (1590 F g−1 at 1 A g−1) and outstanding cycling stability (78.2% retention after 12,000 cycles). Moreover, a prepared hybrid supercapacitor device delivers an energy density of 38.4 W h kg−1 with a power density of 799.9 W kg−1 at 1 A g−1. The results indicate that the obtained high-performance TMPs with hollow structures have an application potential for energy storage devices.
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