BIOGAS PRODUCTION FROM BIODEGRADABLE BIOPLASTICS

In this study, the potential for biogas production from biodegradable bioplastics was evaluated.Mater-Bi ® (a family of maizestarch based flexible films) and PLA (PolyLactic Acid; a rigid, polylactide-based, polymer) bioplastics were digested in laboratory batch reactors, alone or in co-digestion with pig slurry or scotta (partially deproteinized cheese whey), at 35°C or 55°C.Methane (CH4) and hydrogen (H2) production were monitored during the incubation period.Maximum CH4 (Mmax) or H2 (Hmax) production per reactor, potential CH4 (BMP) or H2 (BHP) production g -1 volatile solids (VS), and residual VS in the digestates were determined.Methane was produced when bioplastics were digested alone or with pig slurry, whereas H2 was produced only in co-digestion with scotta.Mmax, BMP, Hmax and BHP were on average higher at 55°C than at 35°C (+69%, +158%, +51% and +45%, respectively).At 35°C, in monodigestion, small amounts of CH4 (33 mL g -1 VS) were produced with Mater-Bi ® only.At 55°C, the BMP for Mater-Bi® and for PLA were equal to 113 mL and 282 mL CH4 g -1 VS, respectively.Monodigestion of Mater-Bi ® and PLA at 55°C reduced the initial VS content by 51%.When PLA was in co-digestion with pig slurry, Mmax was 12% higher than the theoretical one, with a synergistic effect.In co-digestion with scotta, a nearly significant 12% increase in H2 production was observed for Mater-Bi ® incubated at 35°C.The exploitation of bioplastic waste in anaerobic digestion for biogas production, together with or in alternative to conventional composting, appears a promising possibility for a successful waste management.