单层
密度泛函理论
吸附
分子
空位缺陷
化学物理
Atom(片上系统)
屏障激活
化学
催化作用
材料科学
计算化学
结晶学
物理化学
纳米技术
嵌入式系统
有机化学
生物化学
计算机科学
作者
Bin Zhao,Cui Shang,N. D. Qi,Z.Y. Chen,Z.Q. Chen
标识
DOI:10.1016/j.apsusc.2017.03.281
摘要
The stability of various defects in monolayer MoS2, as well as their interactions with free O2 molecules were investigated by density functional theory (DFT) calculations coupled with the nudged elastic band (NEB) method. The defects including S vacancy (monosulfur and disulfue vacancies), antisite defect (MoS) and external Mo atom can exist steadily in monolayer MoS2, and introduce defect levels in these defective systems, which breaks the surface chemical inertness and significantly enhances the adsorption capacity for free O2. The adsorption energy calculations and electronic properties analysis suggest that there is a strong interaction between O2 molecule and defective system. The adsorbed O2 on the defective surface can dissociate with a lower activation energy barrier, which produce two active oxygen atoms. Especially, two Mo atoms can occupy one Mo lattice site, and adsorbed O2 on the top of the Mo atom can then dissociate directly with the lowest activation energy barrier. Hence, our work may provide useful information to design MoS2-based gas sensor or catalysts.
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