硝酸盐
化学
氢氧化锂
化学吸附
无机化学
硝酸锂
共晶体系
碳酸盐
氢氧化物
铁氧体(磁铁)
氧气
分析化学(期刊)
吸附
材料科学
合金
离子
环境化学
离子交换
物理化学
离子键合
有机化学
复合材料
作者
Nan Wang,Fernando Plascencia-Hernández,Daniel G. Araiza,Gabriela Díaz,Heriberto Pfeiffer
标识
DOI:10.1016/j.tca.2023.179496
摘要
Li, Na and K nitrate-containing pentalithium ferrite (Li5FeO4) samples were prepared to evaluate changes of the CO2 capture process at moderate temperatures. These experiments were performed using different CO2 partial pressures and different characterization techniques, such as TG, DSC, XRD and DRIFTS. When using a CO2 saturated atmosphere, all the samples showed high CO2 capture efficiencies at lower temperatures (150–400 °C) than those observed on the pristine Li5FeO4. Specifically, lithium nitrate-containing samples presented the best CO2 capture properties. Thus, this system was further analysed through in-situ DRIFTS and DSC experiments, elucidating the Li5FeO4-CO2 reaction path. Alkali nitrate salts are melted forming eutectic phases with the carbonate produced, where the first one works as an oxygen donor/acceptor, producing reactive intermediate species improving the CO2 capture. Moreover, at the lowest temperatures, H2O presence plays an important role during the whole CO2 capture mechanism, through the lithium hydroxide formation, enabling the process of CO2 chemisorption. Finally, it was proved that Na and K nitrate-containing samples presented similar behaviours than those described for the lithium case, although CO2 capture temperature regimes were shifted depending on the alkaline nitrate.
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