材料科学
三元运算
聚合物
混溶性
能量转换效率
接受者
聚合
化学工程
光电子学
复合材料
物理
计算机科学
工程类
程序设计语言
凝聚态物理
作者
Jing Guo,Xinxin Xia,Beibei Qiu,Jinyuan Zhang,Shucheng Qin,Xiaojun Li,Wenbin Lai,Xinhui Lu,Lei Meng,Zhanjun Zhang,Yongfang Li
标识
DOI:10.1002/adma.202211296
摘要
High-performance all-polymer solar cells (all-PSCs) deeply rely on the joint contributions of desirable optical absorption, adaptive energy levels, and appropriate morphology. Herein, two structural analogous polymerized small-molecule acceptors (PSMAs), PYFCl-T and PYF&PYCl-T, are synthesized, and then incorporated into the PM6:PY-IT binary blends to construct ternary all-PSCs. Due to the superior compatibility of PY-IT and PYFCl-T, the ternary all-PSC based on PM6:PY-IT:PYFCl-T with 10 wt% PYFCl-T, presents higher and more balanced charge mobility, suppressed charge recombination, and faster charge-transfer kinetics, resulting in an outstanding power conversion efficiency (PCE) of 18.12% with enhanced Jsc and FF, which is much higher than that (PCE of 16.09%) of the binary all-PSCs based on PM6:PY-IT. Besides, the ternary all-PSCs also exhibit improved photostability. The conspicuous performance enhancement principally should give the credit to the miscibility-driven phase optimization of the donor and acceptor. These findings highlight the significance of polymer-backbone configuration modulation of PSMAs in morphology optimization toward boosting the device properties of all-PSCs.
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