化学
区域选择性
胺化
基质(水族馆)
氧气
烷氧基
光化学
原子经济
键裂
氧原子
分子
分子氧
组合化学
可见光谱
范围(计算机科学)
有机化学
催化作用
海洋学
烷基
地质学
物理
光电子学
计算机科学
程序设计语言
作者
Jiayang Wang,Bin Shao,Haixia Ge,Yongjin Li,Huan Qi,Li Xiao
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-07-13
卷期号:25 (28): 5333-5338
被引量:2
标识
DOI:10.1021/acs.orglett.3c01910
摘要
An efficient and novel visible-light-induced oxo-amination of terminal alkenes for the construction of α-amino ketones with easily accessible and green O2 as the oxygen source has been developed. The transformation possesses the advantages of operational simplicity, a broad substrate scope, high atom economy, and mild reaction conditions. The mechanistic studies reveal that an energy transfer process probably occurs in the initial stage, and the reaction proceeds via β-scission of the alkoxyl radical species.
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