芦苇
分馏
深共晶溶剂
微波食品加热
共晶体系
溶剂
化学
植物
制浆造纸工业
色谱法
生物
工程类
有机化学
生态学
湿地
电信
合金
作者
Qingsu Xia,Lin Zhang,Peng Zhan,Zhaohui Tong,Yan Qing,Jinzhi He,Zhongbiao Wu,Hui Wang,Lishu Shao,Na Liu
标识
DOI:10.1016/j.renene.2024.120286
摘要
The cost-effective and low-carbon fractionation of lignocellulosic biomass will enhance the economic viability of bio-refining. To achieve efficient reed fractionation under favorable conditions, microwave-assisted choline chloride and p-toluene sulfonic acid (M-ChCl/p-TsOH) pretreatment was employed. The fractionation of reed components demonstrated higher effectiveness with M-ChCl/p-TsOH pretreatment compared to conventional DES pretreatment. Under M-ChCl/p-TsOH conditions, a high hemicellulose removal rate (∼90%) and delignification rate (∼65%) were achieved while achieving a saccharification rate of 88% during cellulase hydrolysis. Microwave assistance not only significantly reduced reaction time to less than 60 s but also enhanced the pretreatment efficacy. Furthermore, the obtained lignin products consisted of low-polymerization lignin (MW < 800 g/mol) and acid-soluble lignin, providing a solid foundation for subsequent high-value utilization of lignin. This study provides a promising strategy for the low carbon fractionation of reed using DES, aiming to simultaneously achieve efficient cellulose hydrolysis and obtain tractable lignin.
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