吸附
孔雀绿
水溶液
朗缪尔吸附模型
罗丹明B
纳米复合材料
中心组合设计
石墨烯
化学工程
Zeta电位
化学
吸热过程
朗缪尔
阳离子聚合
材料科学
核化学
响应面法
色谱法
纳米颗粒
光催化
有机化学
纳米技术
催化作用
工程类
作者
Negar Sadegh,Hedayat Haddadi,Payam Arabkhani,Arash Asfaram,Fatemeh Sadegh
标识
DOI:10.1016/j.molliq.2021.117710
摘要
Many industrial effluents contain various cationic pollutants, including organic dyes with infrangible and stable structures, and are often toxic, posing a severe threat to public health and the environment. In this study, magnetic reduced graphene oxide nanocomposite (RGO/Fe3O4-NC) was used to simultaneously adsorption the mixture of cationic dyes Rhodamine B (Rh B) and Malachite Green (MG) from the aqueous solution. The synthesized adsorbent was characterized by XRD, FTIR, SEM, TEM, VSM, BET-BJH, and zeta potential analyses. In this study, the effect of essential variables such as initial dye concentration, adsorbent dose, contact time, and pH of the solution was optimized using the response surface methodology (RSM) based on central composite design (CCD). The optimum conditions for the adsorption of dyes were pH = 8.0, mixture concentration of each dye 16 mg L−1, contact time 20 min, and adsorbent mass of 0.028 g. The results showed that the equilibrium constant data follow the Langmuir isotherm model with R = 0.99 for both dyes. Adsorption kinetics showed that the adsorption process of the mixture of both dyes was of the second-order type. Also, the thermodynamic parameters revealed that the adsorption process was spontaneous and endothermic. The adsorbent recycling results showed that the adsorbent could be reused for up to 4 cycles with good efficiency. Finally, the prepared magnetic nanocomposite was a promising adsorbent for effective water purification with good adsorption efficiency, magnetically separability, and good recyclability, which can simultaneously eliminate the mixture of dyes.
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