Recent progress on visible-light-driven metal and non-metal doped ZnO nanostructures for photocatalytic degradation of organic pollutants

材料科学 光降解 光催化 掺杂剂 兴奋剂 可见光谱 金属 化学工程 纳米技术 无机化学 催化作用 冶金 光电子学 化学 有机化学 工程类
作者
F. M. Sanakousar,C. C. Vidyasagar,Víctor M. Jiménez‐Pérez,K. Prakash
出处
期刊:Materials Science in Semiconductor Processing [Elsevier BV]
卷期号:140: 106390-106390 被引量:193
标识
DOI:10.1016/j.mssp.2021.106390
摘要

Organic pollutants are chemical compounds that are resistant to degradation in the environment and that treatment methods may not be able to completely remove. Both animals and people may be harmed as a result of their presence. Photocatalysts made of metal oxide semiconductors have promise for environmental cleanup, fuel production from water splitting, and CO2 reduction. Because they are low-cost, non-toxic, and more effective in absorption over a large part of the solar spectrum, ZnO nanostructures are potential photocatalyst candidates for use in photodegradation. The goal of this study is to discuss organic pollutants, photodegradation processes, as well as current developments in ZnO nanostructured preparation methods, such as doping and modification methods, and ZnO as a photocatalyst improvement. When compared to pure ZnO, metal and non-metal doping show better physical and chemical characteristics. The use of different alkaline earth metals, transition metals, noble metals, rare earth metals, and non-metals for doping in the ZnO crystal lattice to create visible-light-responsive doped ZnO photocatalysts is discussed. The impact of dopant type, ionic size, and concentration on the crystal structure, electrical properties, and morphology of doped ZnO with a small bandgap is thoroughly examined. Furthermore, the study examined the effects of different experimental parameters and prospects and challenges have been reported on the degradation of organic pollutants.
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