Derivatives Of ditraizinylamine and tritriazinylamine

Abstract 2‐Arylamino‐4,6‐dichloro‐ s ‐triazine reacts with cyanuric chloride in the presence of alkali to yield N,N ‐bis(4,6‐dichloro‐ s ‐triazin‐2‐yl)‐arylamine. In like manner, 2‐substituted o ‐chloro‐, p ‐chloro‐, o ‐nitro‐ and p ‐carbomethoxyphenylamino‐4,6‐dimethoxy‐ s ‐triazines react with cyanuric chloride to yield the corresponding 4,6‐dichloro‐ s ‐triazin‐2‐yl‐4′,6′‐dimethoxy‐ s ‐triazin‐2′‐ylaryl‐amine, while anilino‐, p ‐toluidino, o ‐ and p ‐methoxyphenylamino and o ‐carbomethoxyphenylamino derivatives did not. The reaction of cyanuric chloride with 2,4‐dichloro‐6‐ethylamino‐ s ‐triazine in the presence of alkali yields the condensation product of the ditriazinylamine type and the reaction of cyanuric chloride with ammonia yields N,N ‐bis(4,6‐dichloro‐ s ‐triazin‐2‐yl)‐ or tris(4,6‐dichloro‐ s ‐triazin‐2‐yl)amine.