塔菲尔方程
制氢
催化作用
分解水
电解水
材料科学
过电位
化学工程
氢
氧化物
氢燃料
铂金
纳米技术
贵金属
电解
化学
电化学
冶金
电极
有机化学
物理化学
工程类
电解质
光催化
作者
Abdul Qayoom Mugheri,Muhammad Rafique Daudpoto,Ali Asghar Sangah,Nasrullah Mugheri,Zeinhom M. El‐Bahy,Yaser A. El‐Badry
标识
DOI:10.1016/j.ijhydene.2021.10.173
摘要
Due to the extensive use of fossil fuels & their direct influence on the environment, new ways of producing energy sources are highly needed. Hydrogen is the perfect candidate for renewable energy; however, H2 gas production is associated with disadvantages due to a lack of efficient and active catalysts that could be cost-effective and comparable to platinum performance. Active hydrogen evolution reaction catalysts are needed to advance the development of a cheaper generation of solar fuels. Thus, outperformance, and stable earth abundant. And inexpensive catalysts are highly demanded. That is H2 gas production from the electrolysis of water through HER. In this work, we present different analytical techniques that characterize an efficient and highly stable catalyst based on transition metal oxide Co3O4/MoS2 nanostructures. And their composites for water splitting in harsh acidic conditions time and material chemical composition as like SEM, EDS, XRD, HRTEM & XPS. The composite material is highly best to produce HER at 10 mA cm−2 and obtained 268 mV overpotential of nano Co3O4/MoS2 (S3) and Tafel slope of 56 mv/dec. Faraday efficiencies of the hydrogen gas production measured for the 60 min and catalyst is highly durable for the 20 h. The presented catalysts are up to the mark of platinum metal performance and superior to several transition metal oxides. This fabrication technology is a new roadmap for developing active and scalable hydrogen-evolving catalysts by overcoming the issues of fewer catalytic edges, low density, and poor conductivity.
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