Enhanced tribocatalytic degradation performance of organic pollutants by Cu1.8S/CuCo2S4 p-n junction

Tribocatalysis research, leveraging the triboelectric effect, presents significant potential for environmental water pollution control. However, there is a notable scarcity of studies pertaining to tribocatalysis involving heterojunctions, particularly in the context of p-n junction tribocatalysis. In this study, we employed a one-step solvothermal method to synthesize a Cu1.8S/CuCo2S4 p-n junction composite catalyst. Subsequently, we explored the tribocatalytic degradation performance of organic pollutants facilitated by the Cu1.8S/CuCo2S4 catalyst. The findings reveal that, under simple magnetic stirring conditions, the degradation rates achieved by the Cu1.8S/CuCo2S4 catalyst for tetracycline (TC), methylene blue (MB), and methyl orange (MO) are remarkably high, reaching 99.9 %, 99.7 %, and 94.0 %, respectively. This underscores the broad applicability of the Cu1.8S/CuCo2S4 catalyst for the tribocatalytic degradation of diverse organic pollutants. Experimental evidence establishes that friction occurring between the polytetrafluoroethylene (PTFE) magnet rod, the beaker, and the catalyst induces charge transfer at their interfaces, generating highly oxidized active species that effectively decompose pollutants. Through free radical capture and electron spin resonance (ESR) tests, it was empirically determined and validated that the principal active species involved in tribocatalytic degradation are holes (h+) and superoxide radicals (O2–). Incorporating insights from the experimental characterization of p-n junctions and density functional theory (DFT) theoretical calculations, we propose a plausible tribocatalytic mechanism for Cu1.8S/CuCo2S4. This research not only contributes novel findings but also serves as a reference for the exploration of innovative heterojunction tribocatalysts.