A practical strategy for fabrication of transparent, robust and environmentally friendly superhydrophobic surfaces for toys and games

Abstract This work presents a practical strategy for fabrication of transparent, robust and environmentally friendly superhydrophobic surfaces for toys and games by a one-step spray coating method. A type of commercial stringed silica nanoparticles (NPs) is chemically modified by a mixture of two fluorine-free silanes, tetraethyl orthosilicate (TEOS) and dodecyltrimethoxysilane (DDTMS) via a sol–gel process with the aid of ammonia as a basic catalyst and a small amount of water in ethanol, resulting in the formation of an amphiphilic solution, suitable for coating a variety of substrate materials such as glass, ceramics, wood, metal, plastics and paper and so on. Polyarylic acid (PAA) is used as a binder to improve the mechanical robustness of the superhydrophobic coating. Effects of silica NPs concentration, mixing order, TEOS/DDTMS ratio, PAA amount and catalyst on the transparency, uniformity, mechanical robustness and superhydrophobicity of the resultant coatings deposited on the glass slides are investigated. The mechanisms for the superhydrophobicity and water-resistance as well as the effects of catalyst and mixing order are discussed. Furthermore, an example of the superhydrophobic surfaces as toys is presented. This work will pave the way for expanding wide applications of the superhydrophobic surfaces towards toys and games. Article Highlights A one-step spray coating method is developed to fabricate transparent, robust and environmentally friendly superhydrophobic surfaces on various substrates Polyacrylic acid (PAA) plays an important role in improv-ing the uniformity and mechanical robustness of the superhydrophobic coating. An example of practical application is presented for the superhydrophobic surfaces as toys and game