Liquid scintillation counting of electrons from internal conversion for quantifying 109Cd activity using a 3-photomultiplier tube system and a specific spectral unfolding

As part of the international key comparison CCRI(II)-K2.Cd-109.2021, the BIPM has implemented a specific method to measure the activity of 109Cd solution - a key radionuclide in the calibration of gamma-ray spectrometers. The counting of electrons from internal conversion was carried out using a liquid scintillation counter based on 3-photomultiplier tubes. In this technique, a major part of the uncertainty comes from the overlap between the conversion electrons peak and the peak at lower energy from the other products of the decay. As a result, the energy resolution that the liquid scintillation system can achieve is the most critical challenge to achieving a precise measurement. The study demonstrates the advantage of producing a sum of the signal from the three photomultipliers to enhance the energy resolution and limit the peak overlap. In addition, the spectrum has been processed by a specific unfolding approach to properly separate the spectral components. Thanks to the method introduced in this study, an activity estimation has been realized with a relative standard uncertainty of 0.5%.