X射线光电子能谱
电解质
锂(药物)
傅里叶变换红外光谱
电化学
一氧化硅
硅
离子
化学工程
化学
热稳定性
材料科学
无机化学
电极
物理化学
有机化学
医学
工程类
内分泌学
作者
Jeremy Wil- Son,Joon-Hyuk Yim,Jaewon Lee
标识
DOI:10.1016/j.elecom.2023.107517
摘要
Herein, fluorinate silicon monoxide (SiO-F) is prepared by heat treatment of SiO with ammonium bifluoride (NH4HF2) at low temperatures to improve the cycling stability of SiO. The fluorination of SiO is confirmed by X-ray photoelectron spectroscopy (XPS) and Fourier-Transform infrared spectroscopy (FT-IR). The SiO-F exhibits higher initial discharge capacity, rate capability, and cycling stability than untreated SiO (pristine SiO). The superior electrochemical performances of the SiO-F are attributed to the formation of a LiF-rich solid electrolyte interphase (SEI) layer formed by the reaction between Li-ion and F-groups on the surface of SiO during the charge and discharge cycle.
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