热固性聚合物
固化(化学)
玻璃化转变
苯酚
催化作用
聚合物
热稳定性
有机化学
化学
共价键
动态共价化学
高分子化学
支化(高分子化学)
分子
材料科学
超分子化学
作者
Stéphanie Engelen,Bram Daelman,Johan M. Winne,Filip Du Prez
标识
DOI:10.1002/marc.202400790
摘要
Aromatic esters are amongst the oldest known chemical motifs that allow for thermal (re)processing of thermosetting polymers. Moreover, phenyl esters are generally known as activated esters that do not require a catalyst to undergo acyl transfer reactions. Even though dynamic aromatic esters find applications in commercialized thermoset formulations, all-aromatic esters have found limited use so far in the design of covalent adaptable networks (CAN) as a result of their high glass transition temperature (T
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