An all-in-one strategy for resource recovery and immobilization of arsenic from arsenic-bearing gypsum sludge

Arsenic (As)-bearing gypsum sludge, one of the most prominent hazardous wastes, has created a myriad of critical problems in human health, waters, soils, and sediments at the global scale. Unfortunately, the reclamation and disposal of As-bearing gypsum sludge have been rarely investigated. This paper aims to explore a novel technology for simultaneous value-added utilization and harmless exploitation of As-bearing gypsum sludge. In the experiment, As-bearing gypsum sludge and anthracite were mixed, granulated, and then roasted in Ar atmosphere. Based on the thermodynamic analysis and experimental results, the As migration mechanism in the As-bearing gypsum sludge was determined during the roasting process. Under optimal conditions, 90% of As phase was volatilized and then recovered in the form of elemental As99.5, and it could act as a chemical product. In addition, As99.5 could be further processed into high-purity As and As2O3 using existing chlorination-rectification-reduction process and oxidation process, respectively, which can be widely used in the treatments of semiconductor material, pigment, and wood. Residual As primarily occurred as Fe-As compounds, but the leached As concentration in the toxicity characteristic leaching procedure was only 0.008 mg/L. Correspondingly, a new As immobilization method that generates Fe-As compounds (α-Fe and AsFe2) is first proposed and then verified, which may be widely used for simultaneous As-bearing solid wastes reduction and improved harmlessness. This paper is significant for development of the metallurgical, mining, acid, and thermal power industries, minimizing its environmental risk.