灰烬
扩散
旋节分解
相(物质)
热力学
三元运算
工作(物理)
材料科学
三元数制
航程(航空)
相图
化学
分析化学(期刊)
计算机科学
物理
有机化学
复合材料
程序设计语言
色谱法
作者
Jing Liu,Weisen Zheng,Xiao-Gang Lu
标识
DOI:10.1016/j.calphad.2022.102430
摘要
The Co–Cu–Fe ternary system was thermodynamically reassessed with the CALPHAD method in the present work. The miscibility gap of the fcc phase at 1373 K was experimentally determined. The phase relationship among the liquid, Cu-rich and Cu-depleted fcc phases was established. Based on the new experiment data and available data in the literature, the thermodynamic optimization of the Co–Cu–Fe system was carried out. The experimental phase equilibria over the whole composition range can be reproduced. Additionally, in order to optimize the temperature-dependent mobility parameters, the interdiffusion coefficients at 1373 K and 1473 K were measured with the diffusion-couple method. Based on the updated thermodynamic description and atomic mobilities in the binary subsystems, the atomic mobilities of Co, Cu and Fe in the fcc phase were re-optimized. The measured composition profiles and diffusion paths of diffusion couples can be well reproduced using the present mobility parameters.
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