Concentration Controlling of Carboxylic Ester‐Based Electrolyte for Low Temperature Lithium‐Ion Batteries

Abstract Low temperature has been a major challenge for lithium‐ion batteries (LIBs) to maintain satisfied electrochemical performance, and the main reason is the deactivation of electrolyte with the decreasing temperature. To address this point, in present work, we develop a low‐temperature resistant electrolyte which includes ethyl acetate (EA) and fluoroethylene carbonate (FEC) as solvent and lithium difluoro(oxalato)borate (LiDFOB) as the primary lithium salt. Due to the preferential decomposition of LiDFOB and FEC, a solid electrolyte interface rich in LiF is formed on the lithium metal anodes (LMAs) and lithium cobalt oxide (LCO) cathodes, contributing to higher stability and rapid desolvation of Li + ions. The batteries with the optimized electrolyte can undergo cycling tests at −40 °C, with a capacity retention of 83.9 % after 200 cycles. Furthermore, the optimized electrolyte exhibits excellent compatibility with both LCO cathodes and graphite (Gr) anodes, enabling a Gr/LCO battery to maintain a capacity retention of 90.3 % after multiple cycles at −25 °C. This work proposes a cost‐effective electrolyte that can activate potential LIBs in practical scenarios, especially in low‐temperature environments.