苋菜
材料科学
电极
电解
化学工程
电化学
图层(电子)
电解质
光催化
分析化学(期刊)
纳米技术
化学
催化作用
色谱法
有机化学
食品科学
物理化学
工程类
作者
Daying Chen,Lin Zhang,Danning Chen,Peng Hou,Jiashu Liu,Chuanbin Wang,Moses Akintayo Aborisade,Meilin Yin,Yongkui Yang
出处
期刊:Chemosphere
[Elsevier]
日期:2023-06-01
卷期号:325: 138380-138380
被引量:6
标识
DOI:10.1016/j.chemosphere.2023.138380
摘要
Efficient, stable, and easily producible electrodes are useful for treating dye wastewater through electrochemical oxidation. In this study, an Sb-doped SnO2 electrode with TiO2 nanotubes as the middle layer (TiO2-NTs/SnO2–Sb) was prepared through an optimized electrodeposition process. Analyses of the coating morphology, crystal structure, chemical state, and electrochemical properties revealed that tightly packed TiO2 clusters provided a larger surface area and more contact points, which is conducive to reinforcing the binding of SnO2–Sb coatings. Compared with a Ti/SnO2–Sb electrode without a TiO2-NT interlayer, the catalytic activity and stability of the TiO2-NTs/SnO2–Sb electrode significantly improved (P < 0.05), as reflected by the 21.8% increase in the amaranth dye decolorization efficiency and 200% increase in the service life. The effects of current density, pH, electrolyte concentration, initial amaranth concentration, and the interaction between various combinations of parameters on the electrolysis performance were investigated. Based on response surface optimization, the maximum decolorization efficiency of the amaranth dye could reach 96.2% within 120 min under the following set of optimized parameter values: 50 mg L−1 amaranth concentration, 20 mA cm−2 current density, and 5.0 pH. A potential degradation mechanism of the amaranth dye was proposed based on the experimental results of a quenching test, ultraviolet–visible spectroscopy, and high-performance liquid chromatography-mass spectrometry. This study provides a more sustainable method for fabricating SnO2–Sb electrodes with TiO2-NT interlayers to treat refractory dye wastewater.
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