Immobilizing ultrafine PtRu alloy nanoparticles onto 3D interconnected MXene-graphene frameworks for highly efficient methanol oxidation

Although direct methanol fuel cell (DMFC) is regarded as a promising power source to establish green energy conversion system, its overall performance is largely limited by the slow methanol oxidation kinetics of current anode catalysts. Herein, we demonstrate a robust and facile bottom-up strategy for the controllable construction of ultrafine PtRu alloy nanoparticles immobilized onto three-dimensional (3D) interconnected Ti3C2Tx MXene-graphene frameworks (PtRu/MXene-G) through a co-assembly process. Interestingly, the utilization of 3D porous MXene-G matrix provides strong interfacial interactions with alloy nanocrystals and promotes the transportation of both reactant and electron during the electrocatalytic process, while the introduction of Ru atoms ameliorates the Pt electronic structure and generates plentiful hydroxyl species for the oxidative removal of CO byproducts. Working together, the resulting PtRu/MXene-G nanoarchitecture with an appropriate Pt/Ru atomic ratio exhibits exceptional methanol oxidation properties in terms of a large electrochemically active surface area of 101.8 m2 g−1, a high mass (specific) activity of 1779.5 mA mg−1 (1.75 mA cm−2), and good long-term stability, all of which are significantly superior to those of conventional Pt/carbon black, Pt/G, Pt/MXene, and Pt/MXene-G catalysts with an identical Pt usage.